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Oxidation of cyclohexene with oxygen catalyzed by a graphite intercalation compound with MoCl/sub 5/. I. Kinetics and mechanism of the decomposition of cyclohexenyl hydroperoxide

Journal Article · · Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5642033
; ; ; ;

The kinetics of the decomposition of cyclohexenyl hydroperoxide (CHHP) has been studied on a graphite intercalation compound with MoCl/sub 5/ in cyclohexene solution in the temperature range 50-75/sup 0/C. A reaction scheme has been proposed, including the participation of the catalyst in the radical decomposition of CHHP and epoxidation by it of cyclohexene. Based on the proposed scheme, kinetic equations have been obtained, which effectively represent the experimental data.

Research Organization:
L. V. Pisarzhevskii Institute of Physical Chemistry, Kiev, USSR
OSTI ID:
5642033
Journal Information:
Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 27:6; ISSN KICAA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKENES
CARBON
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
CLATHRATES
CYCLOALKENES
DECOMPOSITION
ELEMENTAL MINERALS
ELEMENTS
EPOXIDES
EQUATIONS
GRAPHITE
HALIDES
HALOGEN COMPOUNDS
HETEROGENEOUS CATALYSIS
HEXENES
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN PEROXIDE
HYDROXY COMPOUNDS
KETONES
KINETIC EQUATIONS
KINETICS
MINERALS
MOLYBDENUM CHLORIDES
MOLYBDENUM COMPOUNDS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
RADICALS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SEPARATION PROCESSES
TRANSITION ELEMENT COMPOUNDS
YIELDS