Mechanism of the catalytic action of penta(dimethylsulfoxido)vanadyl hexathiocyanatoplatinate in the liquid-phase oxidation of cyclohexene

Journal Article · Fri Jul 10 04:00:00 EDT 1987 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00953840· OSTI ID:5846149

Kholuiskaya, S N; Kasparov, V V; Kovalev, V V; Konovalova, A A; Rubailo, V L

The complex studied - penta(dimethylsulfoxido)vanadyl hexathiocyanatoplatinate (I) is an effective catalyst for the low-temperature oxidation of cyclohexene in alcoholic media, ensuring a high reaction rate up to a high degree of conversion. It has been established that there is a synergism between the component parts of the catalyst, the maximum rate of oxidation of cyclohexene being observed with V/Pt = 2. In the initial stages of the oxidation of cyclohexene in the presence of (I), the reaction rate is described by the kinetics of a chain growth-chain breaking process.

• Research Organization: Institute of Chemical Physics, Moscow, USSR
• OSTI ID: 5846149
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 36:1; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
HETEROGENEOUS CATALYSIS
HEXENES
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDATION
PLATINUM COMPLEXES
REACTION KINETICS
REDOX POTENTIAL
TRANSITION ELEMENT COMPLEXES
VANADIUM COMPLEXES