Oxidative transformations of cyclohexene hydroperoxide catalyzed by penta(dimethylsulfoxido) vanadyl hexathiocyanatoplatinate

Journal Article · Fri Jul 10 04:00:00 EDT 1987 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00953841· OSTI ID:5889131

Kholuiskaya, S N; Rubailo, V L; Emanuel, N M

Oxidation of cyclohexenyl hydroperoxide by molecular oxygen in the presence of penta(dimethylsulfoxido)vanadyl hexathiocyanatoplatinate proceeds at a high rate at low temperatures with the formation of bifunctional, oxygen-containing products. The main route of the reaction is the molecular oxidation of the hydroperoxide with ring opening in a complex (Cat/sub m/...HOOR/sub n/); oxidation of cyclohexenyl hydroperoxide to a dihydroperoxide takes place simultaneously by a chain mechanism.

• Research Organization: Institute of Chemical Physics, Moscow, USSR
• OSTI ID: 5889131
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 36:1; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
CYCLOALKENES
DMSO
HETEROGENEOUS CATALYSIS
HEXENES
HYDROCARBONS
KINETICS
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PEROXIDES
PLATINUM COMPLEXES
REACTION KINETICS
SULFOXIDES
TRANSITION ELEMENT COMPLEXES
VANADIUM COMPLEXES