Optoelectronic properties of boron compensated amorphous silicon solar cells
It has been reported by a number of laboratories that the doping of the ''intrinsic'' region of the hydrogenated amorphous silicon solar cells with low levels of boron has a large effect on cell performance. More specifically it has been found that introduction of less than 1 ppm of boron in the amorphous silicon network improves the response of the solar cell in the long wavelength region and adds to their stability on light exposure. High levels of boron lead to the rapid deterioration of cell performance. These phenomena are not yet fully understood. In this paper the authors report the investigation of the optoelctronic properties of reactively sputtered amorphous silicon films and solar cells which were deposited with small amounts of B/sub 2/H/sub 6/ in the Ar-H/sub 2/ discharge. The films studied were produced with variable amounts of hydrogen because hydrogen incorporation affects both the density of dangling bonds as well as the doping efficiency. Emphasis was placed on determining the densities and the nature of states in the gap affecting the optical, recombination and transport properties of these films.
- Research Organization:
- Corporate Research Laboratory, Exxon Research and Engineering Company, Clinton Township, Annandale, NJ
- OSTI ID:
- 6026019
- Report Number(s):
- CONF-840561-
- Journal Information:
- Conf. Rec. IEEE Photovoltaic Spec. Conf.; (United States), Journal Name: Conf. Rec. IEEE Photovoltaic Spec. Conf.; (United States); ISSN CRCND
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
140501* -- Solar Energy Conversion-- Photovoltaic Conversion
AMORPHOUS STATE
ARGON
BENCH-SCALE EXPERIMENTS
BORON
BORON COMPOUNDS
BORON HYDRIDES
CHEMICAL REACTIONS
CRYSTAL DOPING
DENSITY
DEPOSITION
DIRECT ENERGY CONVERTERS
ELECTRICAL PROPERTIES
ELECTROMAGNETIC RADIATION
ELEMENTS
EQUIPMENT
FABRICATION
FILMS
FLUIDS
FUNCTIONS
GASES
GRADED BAND GAPS
HYDRIDES
HYDROGEN COMPOUNDS
HYDROGENATION
NONMETALS
OPTICAL PROPERTIES
PERFORMANCE
PHOTOELECTRIC CELLS
PHOTOVOLTAIC CELLS
PHYSICAL PROPERTIES
RADIATIONS
RARE GASES
RESPONSE FUNCTIONS
SEMIMETALS
SILICON
SILICON SOLAR CELLS
SOLAR CELLS
SOLAR EQUIPMENT
SPUTTERING
THIN FILMS
VISIBLE RADIATION