Synthesis of phosphorus-32 labeled compounds using recoil atoms. II. Synthesis of o,o-diakyl-s-alkylthio (/sup 32/P) phosphates and study of kinetics of thiol group substitution
Journal Article
·
· Sov. Radiochem. (Engl. Transl.); (United States)
OSTI ID:6011456
The authors synthesize O,O-Dialkyl-S-alkylthio ( /sup 32/ P) phosphates in a state without carrier by reactions of phosphorous-32 recoil atoms, formed in the reaction /sup 35/Cl (n, alpha) /sup 32/P in the CCl/sub 4/-alkanol-alkanethiol system. Using radiochromatography, they study the kinetics of substitution of the thiol group in O,Odibutyl-S-butylthio ( /sup 32/ P) phosphate. They determine the hydrolysis and transesterification constants.
- OSTI ID:
- 6011456
- Journal Information:
- Sov. Radiochem. (Engl. Transl.); (United States), Journal Name: Sov. Radiochem. (Engl. Transl.); (United States) Vol. 26:6; ISSN SVRDA
- Country of Publication:
- United States
- Language:
- English
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· Sov. Radiochem. (Engl. Transl.); (United States)
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Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400701* -- Radiochemistry & Nuclear Chemistry-- Hot-Atom Chemistry
ALKANES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
DAYS LIVING RADIOISOTOPES
DECOMPOSITION
HALIDES
HALOGEN COMPOUNDS
HOT ATOM CHEMISTRY
HYDROCARBONS
HYDROLYSIS
ISOTOPES
KINETICS
LABELLED COMPOUNDS
LIGHT NUCLEI
LYSIS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS 32
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
RADIOCHEMISTRY
RADIOCHROMATOGRAPHY
RADIOISOTOPES
REACTION KINETICS
RECOILS
SEPARATION PROCESSES
SOLVOLYSIS
SYNTHESIS
THIOLS
400701* -- Radiochemistry & Nuclear Chemistry-- Hot-Atom Chemistry
ALKANES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
DAYS LIVING RADIOISOTOPES
DECOMPOSITION
HALIDES
HALOGEN COMPOUNDS
HOT ATOM CHEMISTRY
HYDROCARBONS
HYDROLYSIS
ISOTOPES
KINETICS
LABELLED COMPOUNDS
LIGHT NUCLEI
LYSIS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS 32
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
RADIOCHEMISTRY
RADIOCHROMATOGRAPHY
RADIOISOTOPES
REACTION KINETICS
RECOILS
SEPARATION PROCESSES
SOLVOLYSIS
SYNTHESIS
THIOLS