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Phosphorylation of nitrogen heterocycles. X. Azole catalysis in the phosphorylation by phosphorus-32 recoil atoms

Journal Article · · J. Gen. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5675931
; ;
A specific catalytic function was found for azoles in the phosphorylation of alcohols by /sup 32/P recoil atoms due to the intermediate formation of azolido (/sup 32/P)phosphates whose phosphorylating capacity determines the direction of these reactions. The possibility of the Atherton-Todd reaction under nuclear chemical synthesis conditions upon stabilization of phosphorus-32 recoil atoms in the CCl/sub 4/-alkanol-azole system was demonstrated.
Research Organization:
A. M. Gor'kii Perm State Univ., USSR
OSTI ID:
5675931
Journal Information:
J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:1; ISSN JGCHA
Country of Publication:
United States
Language:
English

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Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400701* -- Radiochemistry & Nuclear Chemistry-- Hot-Atom Chemistry
ALCOHOLS
AZOLES
BARYON REACTIONS
BARYONS
CARBON TETRACHLORIDE
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
COMPARATIVE EVALUATIONS
ELEMENTARY PARTICLES
ESTERIFICATION
FAST NEUTRONS
FERMIONS
HADRON REACTIONS
HADRONS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HOT ATOM CHEMISTRY
HYDROXY COMPOUNDS
IRRADIATION
ISOTOPES
LABELLED COMPOUNDS
LABELLING
LIGHT NUCLEI
MATERIALS TESTING
NEUTRON REACTIONS
NEUTRONS
NUCLEAR REACTIONS
NUCLEI
NUCLEON REACTIONS
NUCLEONS
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS CHLORIDES
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOCHEMISTRY
REACTION INTERMEDIATES
RECOILS
STABLE ISOTOPES
TARGETS
TESTING