Synthesis of nitro derivatives of dibenzo-18-crown-6

Journal Article · Wed Jul 20 04:00:00 EDT 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6008210

Kalishevich, V S; Timofeev, O S; Zakharov, K S; Gren', A I

The reaction of dibenzo-18-crown-6 with nitric acid in the presence of lanthanum nitrate in acetontrile led to the production of its nitro derivative 20,25-dinitro-2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene. Possible paths for the synthesis of the mono- and trinitro derivatives of dibenzo-18-crown-6 are analyzed.

• Research Organization: A.V. Bogat-skii Physicochemical Institute, Odessa (USSR)
• OSTI ID: 6008210
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 24:2; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
CATALYSIS
CATALYTIC EFFECTS
COMPLEXOMETRY
DIENES
GLYCOLS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
ISOMERS
LANTHANUM COMPOUNDS
LANTHANUM NITRATES
MASS SPECTRA
MOLECULAR STRUCTURE
MOLYBDENUM COMPOUNDS
MOLYBDENUM NITRATES
NITRATES
NITRATION
NITRIC ACID
NITRO COMPOUNDS
NITROGEN COMPOUNDS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
POLYENES
POLYETHYLENE GLYCOLS
POLYMERS
RARE EARTH COMPOUNDS
REFRACTORY METAL COMPOUNDS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS