Kinetics of the hydroxyethylation of n-octyl alcohol in the presence of the macrocyclic ether dibenzo-18-crown-6
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6773705
A study has been made of the kinetics of the reaction of ethylene oxide with n-octyl alcohol catalyzed by potassium octylate in the presence of the macrocyclic ether dibenzo-18-crown-6. A kinetic model has been proposed, which satisfactorily represents the effect of dibenzo-18-crown-6 on the rate of hydroxyethylation over a wide range of molar ratios of dibenzo-18-crown-6:potassium octylate and initial alcohol concentrations.
- Research Organization:
- D. I. Mendeleev Moscow Chemical Engineering Institute (USSR)
- OSTI ID:
- 6773705
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:4; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKALI METAL COMPLEXES
ALKALI METAL COMPOUNDS
ALKOXIDES
ALKYLATION
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
EQUATIONS
GLYCOLS
HOMOGENEOUS CATALYSIS
HYDROXY COMPOUNDS
HYDROXYLATION
KINETIC EQUATIONS
KINETICS
MATHEMATICAL MODELS
OCTANOLS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
POLYETHYLENE GLYCOLS
POLYMERS
POTASSIUM COMPLEXES
POTASSIUM COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
SOLVATION
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKALI METAL COMPLEXES
ALKALI METAL COMPOUNDS
ALKOXIDES
ALKYLATION
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMPLEXES
EQUATIONS
GLYCOLS
HOMOGENEOUS CATALYSIS
HYDROXY COMPOUNDS
HYDROXYLATION
KINETIC EQUATIONS
KINETICS
MATHEMATICAL MODELS
OCTANOLS
ORGANIC COMPOUNDS
ORGANIC POLYMERS
POLYETHYLENE GLYCOLS
POLYMERS
POTASSIUM COMPLEXES
POTASSIUM COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
SOLVATION