The transformation of organic amines by transition metal cluster compounds

Technical Report · Mon Dec 31 23:00:00 EST 1990

OSTI ID:5959458

Adams, R D

This report from the Department of Chemistry, University of South Carolina contains the following sections: (1) hydrogenation of ynamines by metal cluster complexes; (2) synthesis and characterization of ynamine complexes of dirhenium; (3) ring opening of strained ring thioethers: (a) reaction of thietane with Os{sub 3}(CO){sub 11}NCMe, (b) reaction of 3,3 dimethylthietane with Os{sub 3}(CO){sub 10}(NCMe){sub 2}; (4) CO splitting: The reaction of Mn{sub 2}(CO){sub 9}NCMe with ynamine; and (5) publications under this project in 1990. 16 refs., 9 figs.

• Research Organization: South Carolina Univ., Columbia, SC (USA). Dept. of Chemistry
• Sponsoring Organization: DOE; USDOE, Washington, DC (USA)
• DOE Contract Number: FG09-84ER13296
• OSTI ID: 5959458
• Report Number(s): DOE/ER/13296-7; ON: DE91010622
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYNES
AMINES
CARBONYLS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
DIMERS
DOCUMENT TYPES
HYDROCARBONS
HYDROGENATION
LIGANDS
MANGANESE COMPLEXES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OSMIUM COMPLEXES
PROGRESS REPORT
RHENIUM COMPLEXES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES