The transformation of organic amines by transition metal cluster compounds. Progress report, 1993--1994

Technical Report · Fri Dec 31 23:00:00 EST 1993

DOI:https://doi.org/10.2172/10175474· OSTI ID:10175474

Adams, R D

In the recent year, the authors extended investigations into insertion reactions by investigating the insertion of dicarboxylate acetylene into the metal-metal bond of Re{sub 2}(CO){sub 9}(NCMe). Secondly, the authors considered the ring opening reactions of the cyclic thioethers: tetrahydrothiophene and thiacyclohexane when complexed to Os{sub 3}(CO){sub 10}(NCMe){sub 2}. In a third effort, various osmium complexes of cyclobutynes were synthesized and the subsequent reactivity probed. Finally, energy storage (via absorption of UV-visible photons) in osmium cluster compounds was investigated.

• Research Organization: South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: FG09-84ER13296
• OSTI ID: 10175474
• Report Number(s): DOE/ER/13296--10; ON: DE94017151
• Country of Publication: United States
• Language: English

Related Subjects

14 SOLAR ENERGY
140505
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201
400500
ALKYNES
CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
CHEMICAL REACTIONS
ENERGY STORAGE
ORGANIC SULFUR COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OSMIUM COMPOUNDS
PHOTOCHEMICAL, PHOTOBIOLOGICAL, AND THERMOCHEMICAL CONVERSION
PHOTOCHEMISTRY
PROGRESS REPORT
RHENIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
ULTRAVIOLET RADIATION
VISIBLE RADIATION