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The transformation of organic amines by transition metal cluster compounds

Technical Report ·
DOI:https://doi.org/10.2172/7108222· OSTI ID:7108222

Research continued on transition element complexes. The following chemical reactions are described: sulfido osmium carbonyl clusters containing secondary aminocarbene ligands and catalytic tertiary amine metathesis; aminocarbene ligands formed by the hydrogenation of ynamine ligands; aminocarbene ligands formed by the reaction of Os{sub 3}(CO){sub 10}(H){sub 2} with ynamines; reactions of MeC{sub 2}NMe{sub 2} with Os{sub 4}(CO){sub 12}(S); reactions of MeC{sub 2}NMe{sub 2} with the molecules M{sub 3}(CO){sub 10}(S), (M=Fe, Ru, Os); and studies of the reactions of alkynes with iminium ligands. 12 refs.

Research Organization:
South Carolina Univ., Columbia, SC (USA). Dept. of Chemistry
Sponsoring Organization:
DOE/ER
DOE Contract Number:
FG09-84ER13296
OSTI ID:
7108222
Report Number(s):
DOE/ER/13296-6; ON: DE90008834
Country of Publication:
United States
Language:
English

Similar Records

Cluster complexes containing ynamine ligands. 1. Synthesis and structural characterizations of the complexes Os sub 4 (CO) sub 11 (. mu. sub 3 -MeC sub 2 NMe sub 2 )(. mu. -MeC sub 2 NMe sub 2 )(. mu. sub 3 -S), Os sub 4 (CO) sub 11 (. mu. -C(Me)C(NMe sub 2 )C(NMe sub 2 )CMe)(. mu. sub 3 -S), Os sub 4 (CO) sub 11 (. mu. -C(NMe sub 2 )C(Me)C(Me)C(NMe sub 2 ))(. mu. sub 3 -S), Os sub 4 (CO) sub 9 (. mu. -MeC sub 2 NMe sub 2 )(. mu. -C(Me)C(NMe sub 2 )C(Me)C(NMe sub 2 ))-(. mu. sub 3 -S), and Os sub 3 (CO) sub 7 (. mu. sub 3 -MeC sub 2 NMe sub 2 )(. mu. -MeC sub 2 NMe sub 2 )(. mu. sub 3 -S)
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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYNES
AMINES
CARBENES
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL PREPARATION
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COMPLEXES
DOCUMENT TYPES
HYDROCARBONS
HYDROGENATION
IRON COMPOUNDS
ISOMERIZATION
LIGANDS
MOLECULAR STRUCTURE
MOLECULES
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OSMIUM COMPLEXES
PROGRESS REPORT
RADICALS
REFRACTORY METAL COMPOUNDS
RUTHENIUM COMPOUNDS
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS