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Ligand transformations and catalysis by transition metal cluster compounds containing sulfur: Progress report, 1986

Technical Report ·
OSTI ID:6950847

The following are reported: tertiary amine metathesis catalysis by metal carbonyl clusters containing carbene ligands, studies of the synthesis and transformations of carbene ligands in cluster complexes, transformations of hydrocarbyl ligands bonded to sulfur in polynuclear metal carbonyl complexes, and synthesis of sulfido ruthenium carbonyl complexes containing acetylene ligands and their reactions with small molecules.

Research Organization:
South Carolina Univ., Columbia (USA). Dept. of Chemistry
DOE Contract Number:
FG09-84ER13296
OSTI ID:
6950847
Report Number(s):
DOE/ER/13296-3; ON: DE87006733
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYNES
AMINES
CARBONYLS
CATALYTIC EFFECTS
COMPLEXES
HYDROCARBONS
LIGANDS
ORGANIC COMPOUNDS
OSMIUM COMPLEXES
RESEARCH PROGRAMS
RUTHENIUM COMPLEXES
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES