Heteroorganic furan derivatives. 61. Trimethyl (5-methyl-2-furyl) silane and trimethyl (5-methyl-2-furyl) german

Journal Article · Wed Jul 01 04:00:00 EDT 1987 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00475465· OSTI ID:5926219

Lukevits, E; Ignatovich, L M; Iovel', I G; Gol'dberg, Yu Sh; Shimanskaya, M V

The transformations of trimethyl (5-methyl-2-furyl)silane and trimethyl (5-methyl-2-furyl) germane were studied upon vapor-phase oxidation by atmospheric oxygen on a V-Mo-Ag-O catalyst. Under these conditions, trimethyl(5-formyl-2-furyl)-silane and trimethyl (5-formyl-2-furyl) germane are formed albeit in only 5-7% yield. This low yield is a consequence of the thermal instability of the starting compounds and the aldehydes formed. The oxidation of 2-methyl-5-tert-butylfuran was studied under comparable conditions. The corresponding aldehyde was obtained in 30% yield. A scheme was proposed for the catalytic oxidation of 5-substituted 2-methylfurans.

• Research Organization: Institute of Organic Synthesis, Riga, USSR
• OSTI ID: 5926219
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 23:1; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALDEHYDES
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
FURANS
GERMANIUM COMPLEXES
HETEROCYCLIC COMPOUNDS
MASS SPECTRA
MOLYBDENUM COMPOUNDS
MOLYBDENUM OXIDES
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDATION
OXIDES
OXYGEN COMPOUNDS
REFRACTORY METAL COMPOUNDS
SEPARATION PROCESSES
SILICON COMPLEXES
SILVER COMPOUNDS
SILVER OXIDES
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS
VANADIUM OXIDES
YIELDS