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Transformation of (2-furyl)carbene generated from 2-dichloromethylfuran by the action of potassium tert-butylate

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:6358223
;
Both gem-(2-furyl)chlorocyclopropanes in yields up to 44% and 2-(chloromethylene)-5-tert-butoxy-2,5-2,5-dihydrofuran in yields up to 12% are formed upon the action of potassium tert-butylate on 2-dichloromethylfuran in excess olefin acceptor. This result is attributed to the reaction of the intermediate (2-furyl)chlorocarbene in ambient form.
Research Organization:
N.D. Zelinskii Institute of Organic Chemistry, Moscow, USSR
OSTI ID:
6358223
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:8; ISSN BACCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKALI METAL COMPLEXES
ALKANES
ALKENES
BINDING ENERGY
CARBENES
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE 35
CHLORINE ISOTOPES
CHROMATOGRAPHY
COMPLEXES
CYCLOALKANES
CYCLOALKENES
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
FURANS
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HEXENES
HYDROCARBONS
INFRARED SPECTRA
ISOMERIZATION
ISOTOPES
LEPTONS
LIGHT NUCLEI
MASS SPECTRA
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
POTASSIUM COMPLEXES
RADICALS
SEPARATION PROCESSES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
VALENCE
YIELDS