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Slow positron studies of hydrogen activation/passivation on SiO sub 2 /Si(100) interfaces

Conference ·
OSTI ID:5907278
The hydrogen atoms are one of the most common impurity species found in semiconductor systems owing to its large diffusivity, and are easily incorporated either in a controlled process like in ion implantation or in an uncontrolled process like the one at the fabrication stage. Hydrogen can passivate dangling bonds and dislocations in these systems and hence can be used to enhance the electrical properties. In a SiO{sub 2}/Si system, hydrogen can passivate electronic states at the interface and can alter the fixed or mobile charges in the oxide layer. Since hydrogen is present in almost all of the environments of SiO{sub 2}/Si wafer fabrication, the activation energy of hydrogen atoms is of paramount importance to a proper understanding of SiO{sub 2}/Si based devices and has not been measured on the technologically most important Si(100) face. There are no direct, nondestructive methods available to observe hydrogen injection into the oxide layer and subsequent diffusion. This study uses the positrons as a sensitive'', nondestructive probe to observe hydrogen interaction in the oxide layer and the interface region. We also describe a new way of characterizing the changes in the density of the interface states under a low-temperature annealing using positrons. 9 refs., 6 figs.
Research Organization:
Brookhaven National Lab., Upton, NY (USA)
Sponsoring Organization:
DOE; USDOE, Washington, DC (USA)
DOE Contract Number:
AC02-76CH00016
OSTI ID:
5907278
Report Number(s):
BNL-45987; CONF-910284--3; ON: DE91010974
Country of Publication:
United States
Language:
English