Synthesis and properties of N,N-dialkyl-P-phenylphosphonamidous iodides

Journal Article · Tue Jan 20 04:00:00 EST 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5852033

Kovaleva, T V; Feshchenko, N G

N,N-Dialkyl-P-phenylphosphonamidous iodides are formed in the reactions of phenylphosphonus diiodide with silylated secondary amines. N,N-Dialkyl-P-phenylphosphonamidous iodides react with electrophilic reagents (methyl iodide, benzenesulfonyl azide, and phenyl azide) by the usual schemes with the formation of alkylation and oxidative-imination products. Iodine catalyzes the disproportionation of morpholinophenylphosphinous iodide into dimorphomorpholinophenylphosphinous iodide with iodine are iododimorpholinophenylphosphonium triiodide and phenylphosphonous diiodide.

• Research Organization: Institute of Organic Chemistry, Kiev, USSR
• OSTI ID: 5852033
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:8; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYLATION
AMINES
AZIDO COMPOUNDS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
ELEMENTS
HALOGENS
IODINE
ISOMERIZATION
ISOMERS
ISOTOPES
LIGHT NUCLEI
NMR SPECTRA
NONMETALS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
OXIDATION
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
REDOX POTENTIAL
REDUCTION
SPECTRA
STABLE ISOTOPES
SYNTHESIS
YIELDS