Tetrakis(alkyl- and arylamido)phosphonium iodides
A preparative method has been developed for the synthesis of tetrakis-(alkyl- and arylamido)phosphonium iodides form the appropriate amines, phosphorus, and iodine. On treatment with aqueous alkali or triethylamine, tetrakisarylamidophosphonium iodides are converted into the triarylaminophosphazobenzenes. Alkylation of tetrakis(arylamido)phosphonium iodides with alkyl iodides in alkaline solution has given tetrakis(arylalkylamido)phosphonium iodides. Tetrakis(o-chloroanilido)phosphonium iodide, on treatment with alkyl iodides in alkaline solution, is converted into (bis(N-alkyl-N-o-chlorophenyl)o-chlorophenylamido)phosphazo-o-chlorobenzenes. /sup 31/P NMR spectra were obtained on a Bruker WP-200, external standard 85% H/sub 3/PO/sub 4/, solvent acetone and methanol. /sup 1/H NMR spectra were obtained on a Tesla BS-467, external standard HMDS, solvent deuterochloroform and carbon tetrachloride.
- Research Organization:
- Institute of Organic Chemistry, Kiev (USSR)
- OSTI ID:
- 6909057
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:5; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
ACETONE
ALCOHOLS
ALKYLATION
AMIDES
AMINATION
AMINES
CARBON TETRACHLORIDE
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
DEHALOGENATION
DEUTERIUM COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INFRARED SPECTRA
IODINATION
ISOTOPES
KETONES
LIGHT NUCLEI
METHANOL
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
SYNTHESIS