Unusual behavior of bis(tri(N,N-dimethylamido(imidophosphato)phosphite on alkylation with alkyl iodides

Journal Article · Wed Mar 09 23:00:00 EST 1988 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5971044

Bespal'ko, G K; Koidan, G N; Marchenko, A P; Pinchuk, A M

Bis(tri(N,N-diemthylamido)imidophosphato)phosphite (I) was readily alkylated by alkyl iodides at the oxygen atom of the phosphoryl group to give the novel alkoxy-PH-phosphonium iodides (II). The structure of compound II was confirmed by /sup 31/P and /sup 1/H NMR, and by conversion of the iodide into the phosphite. The starting phosphite was obtained by hydrolyzing bis(tri(N,N dimethylamide)imidophosphato)dimethylamidophosphite (IV). NMR spectra were obtained using the standards hexamethyldisiloxane and 85% H/sub 3/PO/sub 4/.

• Research Organization: Institute of Organic Chemistry, Kiev (USSR)
• OSTI ID: 5971044
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:9; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYLATING AGENTS
ALKYLATION
AMIDES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
DECOMPOSITION
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROGEN COMPOUNDS
HYDROLYSIS
IMIDES
INORGANIC ACIDS
INTERMEDIATE COUPLING
IODIDES
IODINATED ALIPHATIC HYDROCARBONS
IODINATION
IODINE COMPOUNDS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
LYSIS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHOROUS ACID
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
SOLVOLYSIS
SPECTRA
STABLE ISOTOPES