Reaction of N-sulfonyltellurimides with methyl iodide

Journal Article · Sun Sep 20 04:00:00 EDT 1987 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7199891

Naddaka, V I; Avanesyan, K V; Cherkinskaya, M L; Minkin, V I

While developing researches into the reactivity of tellurimides, the authors studied the previously unknown reaction of N-sulonyltellurimides with methyl iodide. The authors established that bis(diphenyltellurium) oxide and N-methyl-p-toluenesulfonamide are formed when the tellurimide is boiled in methyl iodide. Such a direction is evidently due to the fact that the telluronium salt produced during the reaction is readily hydrolyzed at the Te-N bond on account of the presence of traces of moisture in the methyl iodide. However, the heating of the tellurimides with an excess of anhydrous methyl iodide in a sealed tube leads to diaryltellurium diiodides and N,N-dimethylsulfonamides. The PMR spectra of solutions of the substances in deuterochloroform were recorded on a Tesla-BS-487 spectrometer at 80 MHz with HMDS as internal standard. The IR spectra were obtained on a Specord 71-IR instrument in Vaseline oil.

• Research Organization: M. A. Suslov Rostov State Univ. (USSR)
• OSTI ID: 7199891
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:4; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
AMIDES
ANTI-INFECTIVE AGENTS
ANTIMICROBIAL AGENTS
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPLEXES
DRUGS
ELEMENTS
ENERGY
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
IMIDES
INFRARED SPECTRA
IODIDES
IODINATED ALIPHATIC HYDROCARBONS
IODINE COMPOUNDS
METHYL IODIDE
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SEMIMETALS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SULFONAMIDES
TELLURIUM
TELLURIUM COMPLEXES
TELLURIUM COMPOUNDS
TELLURIUM HALIDES
TELLURIUM IODIDES