Synthesis of (polyfluoro-1-hydroxyalkyl)phosphines and 3,5,8-tris-(polyfluoroalkyl)-2,6,7-trioxa-1,4-diphosphabicyclo(2. 2. 2. )-octanes from polyfluorinated aliphatic aldehydes
Journal Article
·
· J. Gen. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5795627
Polyfluoro aliphatic aldehydes react at P-H bonds in phosphines with the formation of (polyfluoro-1-hydroxyalkyl)phosphines, which are stable at room temperature. In the thermolysis of these compounds the main course of the decomposition consists in the elimination of an aldehyde molecule. In the reaction of tris(polyfluoro-1-hydroxylalkyl)phosphines with phosphorus trichloride 3,5,8-tris(polyfluoroalkyl)-2,6,7-trioxa-1,4-diphosphabicyclo(2.2.2)octanes are formed.
- Research Organization:
- Institute of Organic Chemistry, Kiev, USSR
- OSTI ID:
- 5795627
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:10; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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· J. Gen. Chem. USSR (Engl. Transl.); (United States)
·
OSTI ID:5774809
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· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
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Thu Dec 31 23:00:00 EST 1998
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OSTI ID:872168
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALDEHYDES
ALKANES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
CYCLOALKANES
FLUORINATED ALIPHATIC HYDROCARBONS
FLUORINE 19
FLUORINE ISOTOPES
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN 1
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERIZATION
ISOTOPES
J-J COUPLING
KINETICS
LIGHT NUCLEI
MULTIPLETS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOSPHINES
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
SYNTHESIS
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALDEHYDES
ALKANES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
CYCLOALKANES
FLUORINATED ALIPHATIC HYDROCARBONS
FLUORINE 19
FLUORINE ISOTOPES
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN 1
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERIZATION
ISOTOPES
J-J COUPLING
KINETICS
LIGHT NUCLEI
MULTIPLETS
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOSPHINES
PHOSPHORUS 31
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
SYNTHESIS