Reaction of carboranyl boron-centered radicals with phosphites and the addition of carborane-containing and some other phosphoranyl radicals to 3,6-di-tert-butyl-ortho-benzoquinone (in Russian)
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
The preparative photolysis of bis(m-carboran-9-yl)mercury and bis(p-carboran-2-yl)-mercury with trimethyl phosphite leads to the dimethyl esters of m- and p-B-carboranylphosphonic acids. The reaction of carboranyl boron-centered radicals with phosphites occurs through the formation of a phosphoranyl radical. The addition of the phosphoranyl radicals derived from 2,6,7-tris(trichloromethyl)-3,5,8-trioxo-1,4-diphosphabicyclo(2.2.2)octane to 3,6-di-tert-butyl-ortho-benzoquinone was detected. ESR spectroscopy was used to observe the tautomeric transfers of the phosphoranyl group between the ortho-benzoquinone oxygen atoms.
- Research Organization:
- A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow, USSR
- OSTI ID:
- 6226261
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:2; ISSN BACCA
- Country of Publication:
- United States
- Language:
- Russian
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
ACTIVATION ENERGY
AROMATICS
BENZOQUINONES
BORON 11
BORON COMPOUNDS
BORON ISOTOPES
CARBON COMPOUNDS
CARBORANES
CHEMICAL REACTIONS
COMPLEXES
COMPLEXOMETRY
COUPLING
COUPLING CONSTANTS
DECOMPOSITION
ELECTRON SPIN RESONANCE
ENERGY
ESTERS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
INTERMEDIATE COUPLING
ISOMER SHIFT
ISOMERIZATION
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
MAGNETIC RESONANCE
MERCURY COMPLEXES
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHONIC ACID ESTERS
PHOSPHOROUS ACID
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
QUINONES
RESONANCE
STABLE ISOTOPES
SYNTHESIS
400201* -- Chemical & Physicochemical Properties
400500 -- Photochemistry
ACTIVATION ENERGY
AROMATICS
BENZOQUINONES
BORON 11
BORON COMPOUNDS
BORON ISOTOPES
CARBON COMPOUNDS
CARBORANES
CHEMICAL REACTIONS
COMPLEXES
COMPLEXOMETRY
COUPLING
COUPLING CONSTANTS
DECOMPOSITION
ELECTRON SPIN RESONANCE
ENERGY
ESTERS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
INTERMEDIATE COUPLING
ISOMER SHIFT
ISOMERIZATION
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
MAGNETIC RESONANCE
MERCURY COMPLEXES
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHONIC ACID ESTERS
PHOSPHOROUS ACID
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
QUINONES
RESONANCE
STABLE ISOTOPES
SYNTHESIS