Complexes of lanthanum with radical anions of 2,2-bipyridyl and 3,6-di-tert-butyl-o-benzoquinone
Journal Article
·
· Russian Chemical Bulletin
Complexes of a rare-earth element containing only one radical-anion ligand have been synthesized and isolated in pure states for the first time. The LaI{sub 2}(bpy)(THF){sub 3} complex has been prepared from [LaI{sub 2}(THF){sub 3}]{sub 2}(C{sub 10}H{sub 8}) and 2,2-bipyridyl in DME. The semiquinone complex LaI{sub 2}(SQ)(THF){sub 3} has been obtained by reaction of lanthanum iodide with 3,6-di-tert-butyl-o-benzoquinone in THF in the presence of lanthanum powder. ESR spectra of the complexes have been studied.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 245287
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 11 Vol. 44; ISSN RCBUEY; ISSN 1066-5285
- Country of Publication:
- United States
- Language:
- English
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