Synthesis and structure of the cluster cation (Pt/sub 3/(/mu//sub 3/-S)(AuPPh/sub 3/)(/mu//sub 3/-AgCl)(/mu/-Ph/sub 2/PCH/sub 2/PPh/sub 2/)/sub 3/)/sup +/, containing both PtAu and PtAg bonds
Journal Article
·
· Inorg. Chem.; (United States)
Interest in Pt-Au and Pt-Ag compounds is growing because the gold or silver incorporation causes significant changes in the activity and selectivity of platinum catalysts. The reaction of (Pt/sub 3/H(/mu//sub 3/-S)(/mu/-dppm)/sub 3/)/sup +/ (dppm = Ph/sub 2/PCH/sub 2/PPh/sub 2/) with Ph/sub 3/PAu/sup +/ was carried out with the aim of substituting the hydride ligand by the Ph/sub 3/PAu/sup +/ ligand. This aim was not achieved; however, the compound (Pt/sub 3/(/mu//sub 3/-S)(AuPPh/sub 3/)(/mu//sub 3/-AgCl)(/mu/-Ph/sub 2/PCH/sub 2/PPh/sub 2/)/sub 3/)/sup +/ containing the Pt/sub 3/AuAg core was isolated. The synthesis, structure, and spectroscopic properties of this complex are reported. 23 refs., 1 fig., 3 tabs.
- Research Organization:
- Univ. of Glasgow (Scotland)
- OSTI ID:
- 5775774
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 27:24; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
BARYONS
CATALYTIC EFFECTS
COMPLEXES
DATA
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
GOLD COMPLEXES
HADRONS
HETEROCYCLIC COMPOUNDS
INFORMATION
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PLATINUM COMPLEXES
PROTONS
SILVER COMPLEXES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
BARYONS
CATALYTIC EFFECTS
COMPLEXES
DATA
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
GOLD COMPLEXES
HADRONS
HETEROCYCLIC COMPOUNDS
INFORMATION
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PLATINUM COMPLEXES
PROTONS
SILVER COMPLEXES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES