Oxidative addition of H/sub 2/ to the A-frame complex (Tr/sub 2/(CO)/sub 2/(. mu. -S)(Ph/sub 2/PCH/sub 2/PPh/sub 2/)/sub 2/): a reinvestigation
Journal Article
·
· Inorg. Chem.; (United States)
A reinvestigation of the reaction of the A-frame complex (Ir/sub 2/(CO)/sub 2/(..mu..-S)(DPPM)/sub 2/) (DPPM = Ph/sub 2/PCH/sub 2/PPh/sub 2/) with H/sub 2/ using improved spectroscopic techniques is reported herein. It is proposed that the reaction is an oxidative addition of H/sub 2/ at one metal center followed by transfer of one hydride ligand to the other metal and concomitant Ir-Ir bond formation. 23 references, 1 figure, 1 table.
- Research Organization:
- Univ. of Alberta, Edmonton (Canada)
- OSTI ID:
- 6084796
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 27:20; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Sulfur-hydrogen and selenium-hydrogen bond activation by both metal centers in [MM[prime](CO)[sub 3](Ph[sub 2]PCH[sub 2]PPh[sub 2])[sub 2]] (M, M[prime] = Rh, Ir)
Synthesis and reactivity of Ph/sub 2/PCH/sub 2/PPh/sub 2/- (dppm-) stabilized Pd-Co and Pd-Pt-Co clusters. Effect of platinum versus palladium on the neighboring palladium center
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Tue Nov 29 23:00:00 EST 1988
· Inorg. Chem.; (United States)
·
OSTI ID:5775774
Sulfur-hydrogen and selenium-hydrogen bond activation by both metal centers in [MM[prime](CO)[sub 3](Ph[sub 2]PCH[sub 2]PPh[sub 2])[sub 2]] (M, M[prime] = Rh, Ir)
Journal Article
·
Wed Apr 28 00:00:00 EDT 1993
· Inorganic Chemistry; (United States)
·
OSTI ID:6259691
Synthesis and reactivity of Ph/sub 2/PCH/sub 2/PPh/sub 2/- (dppm-) stabilized Pd-Co and Pd-Pt-Co clusters. Effect of platinum versus palladium on the neighboring palladium center
Journal Article
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Wed Apr 20 00:00:00 EDT 1988
· Inorg. Chem.; (United States)
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OSTI ID:5708148
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
AROMATICS
CARBONYLS
CHEMICAL REACTIONS
COMPLEXES
DATA
DEUTERIUM
ELEMENTS
EXPERIMENTAL DATA
HYDROGEN
HYDROGEN ISOTOPES
INFORMATION
IRIDIUM COMPLEXES
ISOTOPES
ISOTOPIC EXCHANGE
LIGHT NUCLEI
NONMETALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
STABLE ISOTOPES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
AROMATICS
CARBONYLS
CHEMICAL REACTIONS
COMPLEXES
DATA
DEUTERIUM
ELEMENTS
EXPERIMENTAL DATA
HYDROGEN
HYDROGEN ISOTOPES
INFORMATION
IRIDIUM COMPLEXES
ISOTOPES
ISOTOPIC EXCHANGE
LIGHT NUCLEI
NONMETALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
STABLE ISOTOPES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPLEXES