Structure and behavior of paramagnetic centers in cadmium azide

Journal Article · Wed Jul 01 04:00:00 EDT 1987 · High Energy Chem. (Engl. Transl.); (United States)

OSTI ID:5775651

Egorov, A V; Mukhin, V N; Ryabykh, S M

The paramagnetic centers in irradiated cadmium azide at 77 K, their thermal conversion and formation kinetics have been studied by EPR. The particles N, Cd/sub 2//sup 3 +/, and Cd/sub 3//sup 5 +/ have been identified. The principal values of the spin Hamiltonians have been determined. It is shown that an increase in temperature leads to the destruction of the paramagnetic centers specified above and the formation of new ones.

• Research Organization: Kemerovo State Univ., USSR
• OSTI ID: 5775651
• Journal Information: High Energy Chem. (Engl. Transl.); (United States), Journal Name: High Energy Chem. (Engl. Transl.); (United States) Vol. 21:1; ISSN HIECA
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360602 -- Other Materials-- Structure & Phase Studies
360605* -- Materials-- Radiation Effects
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ANGULAR MOMENTUM
AZIDES
CADMIUM COMPOUNDS
CADMIUM ISOTOPES
CAPTURE
CRYSTAL DEFECTS
CRYSTAL STRUCTURE
CRYSTALS
ELECTROMAGNETIC RADIATION
ELECTRON SPIN RESONANCE
ELECTRONIC STRUCTURE
ELEMENTS
GAMMA RADIATION
HAMILTONIANS
HOLES
HYPERFINE STRUCTURE
IONIZING RADIATIONS
IRRADIATION
ISOTOPE RATIO
ISOTOPES
MAGNETIC RESONANCE
MAGNETISM
MATHEMATICAL OPERATORS
NITROGEN
NITROGEN COMPOUNDS
NONMETALS
PARAMAGNETISM
PARTICLE PROPERTIES
PHYSICAL RADIATION EFFECTS
POINT DEFECTS
POLYCRYSTALS
QUANTUM OPERATORS
RADIATION EFFECTS
RADIATIONS
RESONANCE
SPIN
TEMPERATURE DEPENDENCE
TRAPS
VACANCIES
YIELDS