Paramagnetic centers in irradiated ammonium nitrate
Journal Article
·
· High Energy Chemistry
OSTI ID:224076
The EPR spectra of irradiated single crystals of NH{sub 4}NO{sub 3} were obtained. The paramagnetic centers NO{sub 3}, ONOO, N0{sub 3}{sup 2-} at 77 K, and NO{sub 2} observed in the 160-290 K region were identified. The doublet of bands of 220 < T < 250 K was hypothetically assigned to the formation of an OH radical. The parameters of the EPR spectra and orientation of the radicals in the crystal lattice were determined. The initial radiochemical yields of NO{sub 3}, ONOO, and NO{sub 3}{sup 2-} radicals were estimated. 10 refs., 2 figs., 2 tabs.
- OSTI ID:
- 224076
- Journal Information:
- High Energy Chemistry, Journal Name: High Energy Chemistry Journal Issue: 5 Vol. 25; ISSN 0018-1439; ISSN HIECAP
- Country of Publication:
- United States
- Language:
- English
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