Selective hydrogenation of dienes and alkynes to alkenes in the presence of products of the reaction of bis-. pi. -allylpalladium chloride with amines
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5659633
The authors have shown that the interaction of bis-..pi..-allylpalladium chloride with primary or secondary amines containing alkyl groups of substantial size (octyl- or dioctylamine) in toluene medium leads to the formation of palladium complexes active in the homogeneous catalytic hydrogenation of unsaturated hydrocarbons.
- Research Organization:
- A. V. Topchiev Institute of Petrochemical Synthesis, Moscow, USSR
- OSTI ID:
- 5659633
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 27:6; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Patent
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Mon Feb 16 23:00:00 EST 1981
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OSTI ID:6394835
Supported catalysis for the selective hydrogenation of conjugated dienes and alkynes to alkenes consisting of products of the reduction of a complex of palladium chloride with a primary amine by an organoaluminum compound
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· Kinet. Catal. (Engl. Transl.); (United States)
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OSTI ID:5228381
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
ALKYLATED AROMATICS
ALKYNES
AMINES
AROMATICS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
DIENES
HALIDES
HALOGEN COMPOUNDS
HOMOGENEOUS CATALYSIS
HYDROCARBONS
HYDROGENATION
KINETICS
ORGANIC COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
POLYENES
REACTION KINETICS
TOLUENE
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* -- Chemical & Physicochemical Properties
ALKENES
ALKYLATED AROMATICS
ALKYNES
AMINES
AROMATICS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
COMPLEXOMETRY
DIENES
HALIDES
HALOGEN COMPOUNDS
HOMOGENEOUS CATALYSIS
HYDROCARBONS
HYDROGENATION
KINETICS
ORGANIC COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
POLYENES
REACTION KINETICS
TOLUENE
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS