Supported catalysis for the selective hydrogenation of conjugated dienes and alkynes to alkenes consisting of products of the reduction of a complex of palladium chloride with a primary amine by an organoaluminum compound
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5228381
The effects of the nature of the support, solvent, and surface palladium content on the activity of conjugated dienes and alkynes to alkenes in hydrogenation were studied. These supported palladium complexes have high stability, do not lose activity upon oxygen treatment, and are relatively stable toward heating.
- Research Organization:
- A.V. Topchiev Institute of Petrochemical Synthesis
- OSTI ID:
- 5228381
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 26:5; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKENES
ALKYNES
CATALYSIS
CATALYST SUPPORTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DIENES
HALIDES
HALOGEN COMPOUNDS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGENATION
KINETICS
ORGANIC COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
POLYENES
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKENES
ALKYNES
CATALYSIS
CATALYST SUPPORTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DIENES
HALIDES
HALOGEN COMPOUNDS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGENATION
KINETICS
ORGANIC COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
POLYENES
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS