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New palladium-catalyzed reactions of unsaturated triflates with alkenes and alkynes

Conference ·
OSTI ID:250070
 [1]
  1. Universita degli Studi La Sapienza, Roma (Italy)

After the discovery that vinyl triflates can be used as precursors of {sigma}-vinylpalladium complexes in the reaction with alkenes (Heck reaction) and the development by Stille and co-workers of the cross-coupling reaction of vinyl triflates with organostannanes the triflate-based palladium chemistry has grown tremendously and now this methodology represents a valuable tool in organic synthesis. As part of a continuing interest in this area, the authors report some of the recent results obtained in the reaction of unsaturated triflates with alkenes and alkynes.

OSTI ID:
250070
Report Number(s):
CONF-9508100--
Country of Publication:
United States
Language:
English

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