Palladium catalysts for selective hydrogenation of acetylenes, produced via complexation in an adsorbed layer
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:7148713
A procedure is proposed for the preparation of heterogenized palladium catalysts from palladium chloride and allyl alcohol in an adsorbed layer of the surface of a support (Al/sub 2/O/sub 3/ or MgO), in which the palladium ..pi..-allyl complex, anchored to the support, decomposes at 200 degrees. In catalytic and physicochemical properties these catalysts are practically the same as the palladium catalysts obtained directly from bis(..pi..-allylpalladium chloride).
- Research Organization:
- N.D. Zelinskii Institute of Organic Chemistry, Acad. of Sci., Moscow
- OSTI ID:
- 7148713
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 27:2,PT. 2; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Variation of the selectivity of the action of palladium catalysts deposited on rare-earth oxides in the hydrogenation of acetylenic alcohols
Journal Article
·
Thu Aug 20 00:00:00 EDT 1987
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
·
OSTI ID:5675946
Selective hydrogenation of dienes and alkynes to alkenes in the presence of products of the reaction of bis-. pi. -allylpalladium chloride with amines
Journal Article
·
Mon Jun 01 00:00:00 EDT 1987
· Kinet. Catal. (Engl. Transl.); (United States)
·
OSTI ID:5659633
Variation of the selectivity of the action of palladium catalysts deposited on rare-earth oxides in the hydrogenation of acetylenic alcohols
Journal Article
·
Wed Dec 09 23:00:00 EST 1987
· J. Org. Chem. USSR (Engl. Transl.); (United States)
·
OSTI ID:6160643
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ABSORPTION
ACETYLENE
ALKALINE EARTH METAL COMPOUNDS
ALKENES
ALKYNES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
ELEMENTS
ETHYLENE
HETEROGENEOUS CATALYSIS
HIGH TEMPERATURE
HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGENATION
INORGANIC ACIDS
MAGNESIUM COMPOUNDS
MAGNESIUM OXIDES
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PALLADIUM COMPOUNDS
SUBSTRATES
SYNTHESIS
TEMPERATURE EFFECTS
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ABSORPTION
ACETYLENE
ALKALINE EARTH METAL COMPOUNDS
ALKENES
ALKYNES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
ELEMENTS
ETHYLENE
HETEROGENEOUS CATALYSIS
HIGH TEMPERATURE
HYDROCARBONS
HYDROCHLORIC ACID
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGENATION
INORGANIC ACIDS
MAGNESIUM COMPOUNDS
MAGNESIUM OXIDES
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PALLADIUM COMPOUNDS
SUBSTRATES
SYNTHESIS
TEMPERATURE EFFECTS
TRANSITION ELEMENT COMPOUNDS