Catalysis of liquid-phase dehydrochlorination of 1,1,2-trichloroethane

Journal Article · Fri Jul 10 00:00:00 EDT 1987 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5571907

Shavanov, S S; Tolstikov, G A; Viktorov, G A; Shutenkova, T V

It was shown that vinylidene chloride can be obtained in virtually quantitative yield by the use of triethylbenzylammonium alkoxides as catalysts of 1,1,2-trichloroethane dehydrochlorination. Catalyst anions containing an unsaturated carbon bond in the position relative to oxygen increase catalyst activity. The catalyst is present in the organic phase and is not transferred from one phase into the other.

• OSTI ID: 5571907
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Appl. Chem. USSR (Engl. Transl.); (United States) Vol. 60:1; ISSN JAPUA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
ALKOXIDES
AMINES
AMMONIUM COMPOUNDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINATED ALIPHATIC HYDROCARBONS
COMPARATIVE EVALUATIONS
DECHLORINATION
DEHALOGENATION
DEHYDROGENATION
HALOGENATED ALIPHATIC HYDROCARBONS
HOMOGENEOUS CATALYSIS
HYDROGEN COMPOUNDS
HYDROXIDES
KINETICS
MONOMERS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXYGEN COMPOUNDS
QUATERNARY COMPOUNDS
REACTION KINETICS
REGENERATION
SODIUM COMPOUNDS
SODIUM HYDROXIDES
SYNTHESIS
VINYL MONOMERS
YIELDS