New ligand-bridged polyruthenium(II) complexes with cofacial tetrapyrazolic macrocycles
Journal Article
·
· Inorg. Chem.; (United States)
Three binuclear Ru(II) bimacrocyclic cofacial complexes X(TZ)Ru(bpy)Ru(TZ)X(PF/sub 6/)/sub 4/ (TZ = 2,7,12,17-tetramethyl-1,6,11,16-tetraazaporphyrinogen; X = Me/sub 2/SO, CH/sub 3/CN, or pyridine; bpy = 4,4'-bipyridine) and two tetranuclear tetramacrocylic homologues have been prepared in order to study their capacities as electron carriers. /sup 1/H NMR data and redox potential measurements show that no interaction occurs between the metal centers under these experimental conditions. The insertion in bilayer lipid membranes gives rise to stationary photocurrents of small amplitude.
- Research Organization:
- Universite des Sciences et Techniques du Languedoc, Montpellier, France
- OSTI ID:
- 5532344
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:11; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
New complexes of ruthenium(II) with a tetrapyrazolic macrocycle
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Journal Article
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Wed May 21 00:00:00 EDT 1986
· Inorg. Chem.; (United States)
·
OSTI ID:5582679
Resonance Raman spectroscopy of the lowest excited state of derivatives of tris(2,2'-bipyridine)ruthenium(II): substituent effects on electron localization in mixed-ligand complexes
Journal Article
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Tue Feb 11 23:00:00 EST 1986
· Inorg. Chem.; (United States)
·
OSTI ID:5863199
Photochemical ligand loss as a basis for imaging and microstructure formation in a thin polymeric film
Journal Article
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Tue Dec 18 23:00:00 EST 1990
· Journal of the American Chemical Society; (United States)
·
OSTI ID:5638625
Related Subjects
14 SOLAR ENERGY
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
AZINES
CARBOXYLIC ACIDS
CHEMICAL PREPARATION
COMPLEXES
CURRENTS
DATA
ELECTRIC CURRENTS
ELECTRON TRANSFER
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
INFORMATION
LATTICE PARAMETERS
LIGANDS
MAGNETIC RESONANCE
MEMBRANES
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOCURRENTS
PORPHYRINS
PYRIDINES
REDOX POTENTIAL
RESONANCE
RUTHENIUM COMPLEXES
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400500* -- Photochemistry
AZINES
CARBOXYLIC ACIDS
CHEMICAL PREPARATION
COMPLEXES
CURRENTS
DATA
ELECTRIC CURRENTS
ELECTRON TRANSFER
EXPERIMENTAL DATA
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
INFORMATION
LATTICE PARAMETERS
LIGANDS
MAGNETIC RESONANCE
MEMBRANES
NMR SPECTRA
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOCURRENTS
PORPHYRINS
PYRIDINES
REDOX POTENTIAL
RESONANCE
RUTHENIUM COMPLEXES
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPLEXES