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New complexes of ruthenium(II) with a tetrapyrazolic macrocycle

Journal Article · · Inorg. Chem.; (United States)
OSTI ID:5582679
The preparation and properties of Ru(II) complexes Ru(TZ)XY(PF/sub 6/)/sub 2/ are described (TZ = 2,7,12,17-tetramethyl-1,6,11,16-tetraazaporphyrinogen; X = Me/sub 2/SO, Y = Me/sub 2/SO or pyridine; X = CH/sub 3/CN, Y = CH/sub 3/CN or pyridine; X = Y = pyridine or 4,4'-bipyridine). Thermal and photochemical labilizations of the axial ligands X and Y are studied. /sup 1/H NMR spectroscopy allows easy complex structural characterization. Electronic spectral data and redox potential measurements are discussed.
Research Organization:
Universite des Sciences et Techniques du Languedoc, Montpellier, France
OSTI ID:
5582679
Journal Information:
Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:11; ISSN INOCA
Country of Publication:
United States
Language:
English