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U.S. Department of Energy
Office of Scientific and Technical Information

Fossil energy program. I. Mining research and development: coal preparation and analysis. I. Advanced research and technology development. Technical progress report, 1 April-30 June 1979

Technical Report ·
DOI:https://doi.org/10.2172/5518006· OSTI ID:5518006

Progress is reported in: coal preparation and analysis (microstructure of coal, selective enhancement of magnetic susceptibility of pyrite in coal by dielectric heating, rapid analysis of mineral content of coals (on-line monitoring instrument for pyrite and ash in coal), and coal blending experiments). Developmental research of the chlorination and sintering processes for recovery of minerals from coal fly ash was continued. Low temperature, 500 to 700/sup 0/C, chlorination of fly ashes and of oxide mixtures shows that iron oxide is much more reactive than alumina at these temperatures and hence can be removed preferentially. Investigation of the lime-soda sinter process revealed that the sintering reactions occur by solid phase diffusion of the reacting oxides. For mixtures of lime, silica, and alumina, homogeneous products resulted after sintering for two hours at 1350/sup 0/C. Fly ash magnetic separation tests using a range of electromagnet power settings show that with increased power the mass of the magnetic fraction increases but the average iron content in this fraction decreases. Nonmagnetic fraction fly ash samples were divided into size fractions by a settling technique. Results of the analyses of these fractions indicate that the alumina concentration is highest in the small size fractions; silica and iron oxide concentrations are more independent of size. Design and operation of the chlorination reactor in the HiChlor process will be influenced by these results.

Research Organization:
Ames Lab., IA (USA)
DOE Contract Number:
W-7405-ENG-82
OSTI ID:
5518006
Report Number(s):
IS-4711
Country of Publication:
United States
Language:
English