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Title: Advanced research and technology direct utilization: recovery of minerals from coal fly ash. Fossil energy program technical progress report, 1 April 1981-30 June 1981

Technical Report ·
OSTI ID:6263056

The purpose of this research is to develop methods to process fly ash for (1) the separation and use of an iron-rich fraction; (2) the recovery of metals (primarily Al, Fe, and Ti); and (3) the use of the process residues. During this report period, research on the HiChlor process for the high-temperature chlorination of fly ash included investigation of prechlorinations using Cl/sub 2/-CO gas mixtures to selectively remove iron and titanium, and the physical characterization of fly ash pellets. Gas diffusion coefficients, surface areas, and pore size distributions were measured for both gamma-alumina and fly ash pellets. Experiments on the high temperature sintering of limestone-fly ash mixtures include alumina extractions from sinters prepared using waste materials. High alumina recoveries were obtained for sinters prepared using cement kiln dust as the lime source, and with small amounts of coal refuse added as a mineralizer. Sinter feed mixtures prepared from fly ash, kiln dust, and soda ash were also tested. X-ray diffraction measurements were used to identify the soluble and insoluble compounds found in the clinkers produced. Research has been initiated on methods to agglomerate fly ash mixtures for processing. Agglomerators rather than finely-divided powder mixtures will be more easily handled, transported, and processed. Feed mixtures for both the lime-sinter and HiChlor processes are being studied. A balling disc unit is being used to form agglomerate spheroids. A theoretical analysis of the magnetic separation of fly ash has been completed.

Research Organization:
Ames Lab., IA (USA)
DOE Contract Number:
W-7405-ENG-82
OSTI ID:
6263056
Report Number(s):
IS-4777; ON: DE82003133
Country of Publication:
United States
Language:
English