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Spectrophotometric determination of some carbohydrates, thiocarbonyls and hydrazines

Journal Article · · Analytical Letters
 [1]
  1. Ain Shams Univ. Ciaro (Egypt)
A spectrophotometric method for the determination of microgram amounts of some carbohydrates, thiocarbonyls and hydrazines was developed. It is based on the reaction of these compounds with either cerium (IV) or dichromate. The excess oxidant is allowed to react with iron (II) as a reductant and hexacyanoferrate (III) to develop Prussian blue color with maximum absorption at 700 nm. The optimum procedural conditions and stoichiometry are investigated. Analysis of sample sizes down to 50 {mu}g shows an average recovery of 97% and a relative standard deviation of 1%.
Sponsoring Organization:
USDOE
OSTI ID:
54516
Journal Information:
Analytical Letters, Journal Name: Analytical Letters Journal Issue: 10 Vol. 27; ISSN ANALBP; ISSN 0003-2719
Country of Publication:
United States
Language:
English

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