Reaction of 2,4-dialkoxy- and 2,4-bisalkylamino-1,2,4-azadiphosphetidines with diacetyl

Journal Article · Sat May 10 04:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5416649

Monin, E A; Novikova, Z A; Kabachnik, M M; Lutsenko, A I; Lutsenko, I F

In this work the authors report the reaction of diacetyl with azadiphosphetidines, previously obtained by them, which contained alkoxy and amino groups on the phosphorus atom. It was found that 2,4-dialkoxy and 2,4-bisalkylamino- 1,2,4-azaphosphetidines react with one equivalent of diacetyl in methylene chloride at -78/sup 0/C with the formation of the spirophosphoranes. The composition and structure of the spirophosphoranes were confirmed by elemental analysis and by /sup 31/P, /sup 1/H and /sup 13/C NMR spectroscopy.

• Research Organization: M. V. Lomonosov Moscow State Univ. (USSR)
• OSTI ID: 5416649
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 55:11; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AMINES
CARBON 13
CARBON ISOTOPES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COUPLING
COUPLING CONSTANTS
DIAZO COMPOUNDS
EVEN-ODD NUCLEI
HYDROGEN 1
HYDROGEN ISOTOPES
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
KETONES
LIGHT NUCLEI
METHYLENE CHLORIDE
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES