Reactions of. cap alpha. -phosphorylated carbonyl compounds with amino alcohols

Journal Article · Mon Oct 20 04:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5286419

Moskva, V V; Sitdikova, T Sh; Zykova, T V; Alparova, M V; Shagvaleev, F Sh

2-Aminoethanol reacts with carbonyl compounds with the formation, depending on the structure of the latter, either of a mixture of azomethines and oxazolidines, or of only azomethines. In the development of investigations on the reactivity of ..cap alpha..-phosphorylated carbonyl compounds the authors studied the reactions of a number of amino alcohols with phosphorylated acetaldehyde and acetone. In both cases they observed the formation of compounds of enamine structure, oxazolidines and azomethines were not observed. By means of NMR spectroscopy they established clearly the formation of the E-isomeric products. The /sup 1/H, /sup 31/P, and /sup 13/C NMR spectra were recorded on a WP-80 spectrometer. Chemical shifts of protons and /sup 13/C nuclei are given relative to TMS, and phosphorus nuclei relative to orthophosphoric acid.

• Research Organization: S. M. Kirov Kazan' Institute of Chemical Technology (USSR)
• OSTI ID: 5286419
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:5; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACETALDEHYDE
ACETONE
ALCOHOLS
ALDEHYDES
AMINES
CARBON 13
CARBON ISOTOPES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPARATIVE EVALUATIONS
COUPLING
COUPLING CONSTANTS
DEHYDROCYCLIZATION
EVEN-ODD NUCLEI
HYDROGEN 1
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
KETONES
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
SPECTRA
STABLE ISOTOPES