Method for detecting trace impurities in gases
Patent
·
OSTI ID:5406598
A technique for considerably improving the sensitivity and specificity of infrared spectrometry as applied to quantitative determination of trace impurities in various carrier or solvent gases is presented. A gas to be examined for impurities is liquefied and infrared absorption spectra of the liquid are obtained. Spectral simplification and number densities of impurities in the optical path are substantially higher than are obtainable in similar gas-phase analyses. Carbon dioxide impurity (approx. 2 ppM) present in commercial Xe and ppM levels of Freon 12 and vinyl chloride added to liquefied air are used to illustrate the method.
- DOE Contract Number:
- W-7405-ENG-36
- Assignee:
- TIC; ERA-05-029376; EDB-80-084706
- OSTI ID:
- 5406598
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ABSORPTION SPECTROSCOPY
GASES
IMPURITIES
CARBON DIOXIDE
CHEMICAL ANALYSIS
CHLORINATED ALIPHATIC HYDROCARBONS
FREONS
INFRARED SPECTRA
SENSITIVITY
VINYL MONOMERS
XENON
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
ELEMENTS
FLUIDS
HALOGENATED ALIPHATIC HYDROCARBONS
MONOMERS
NONMETALS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RARE GASES
REFRIGERANTS
SPECTRA
SPECTROSCOPY
WORKING FLUIDS
400104* - Spectral Procedures- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ABSORPTION SPECTROSCOPY
GASES
IMPURITIES
CARBON DIOXIDE
CHEMICAL ANALYSIS
CHLORINATED ALIPHATIC HYDROCARBONS
FREONS
INFRARED SPECTRA
SENSITIVITY
VINYL MONOMERS
XENON
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
ELEMENTS
FLUIDS
HALOGENATED ALIPHATIC HYDROCARBONS
MONOMERS
NONMETALS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RARE GASES
REFRIGERANTS
SPECTRA
SPECTROSCOPY
WORKING FLUIDS
400104* - Spectral Procedures- (-1987)