Reactions of adducts of phosphorus pentachloride and 1-alkenes with arsenic trifluoride

Journal Article · Mon Oct 20 00:00:00 EDT 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5286435

Fridland, S V; Miftakhov, M N; Dmitrieva, N V

As a result of NMR investigations of models of sigma and ..pi.. nu complexes of 1-heptene (or 1-hexene) and phosphorus pentachloride in reactions with arsenic trifluoride it was shown that the formation of the phosphorus-containing arylated product by the Friedel-Crafts scheme is possible only with the participation of the sigma complex, but in the case of the ..pi.. nu complex the arylation of the olefin occurs.

• Research Organization: S. M. Kirov Kazan' Institute of Chemical Technology (USSR)
• OSTI ID: 5286435
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 56:5; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ALKENES
ARSENIC COMPOUNDS
ARSENIC FLUORIDES
ARYLATION
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXOMETRY
COUPLING
COUPLING CONSTANTS
FLUORIDES
FLUORINE COMPOUNDS
FRIEDEL-CRAFTS REACTION
HALIDES
HALOGEN COMPOUNDS
HEPTENES
HYDROCARBONS
INTERMEDIATE COUPLING
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS CHLORIDES
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
SPECTRA
STABLE ISOTOPES