Reaction of divinyl ether with phosphorus pentachloride

Journal Article · Sat Oct 10 04:00:00 EDT 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5025147

Rozinov, V G; Kolbina, V E; Donskikh, V I

It is known that divinyl sulfides are phosphorylated by phosphorus pentachloride with the formation of 1,4-thiaphosphorin derivatives. The authors have found that divinyl ether is phosphorylated by phosphorus pentachloride in a benzene medium with the formation of 4,4-dichloro-4H-1,4-oxaphosphorin-4-ium hexachlorophosphate; the process goes analogously to the phosphorylation of divinyl sulfide. The /sup 1/H, /sup 31/P, and /sup 13/C NMR spectra were recorded on a Bruker WP-200SY spectrometer at room temperature. Stabilization was effected by the signal of deuterium in CDCl/sub 3/. The /sup 31/P signals were recorded relative to 85% H/sub 3/PO/sub 4/ as external standard.

• Research Organization: A. A. Zhdanov Irkut-sk State Univ. (USSR)
• OSTI ID: 5025147
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:4; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
AROMATICS
BENZENE
CARBON 13
CARBON ISOTOPES
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINATION
CHLORINE COMPOUNDS
CHLOROFORM
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
ETHERS
EVEN-ODD NUCLEI
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROCARBONS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
INTERMEDIATE COUPLING
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS CHLORIDES
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS