Synthesis of 1,3,4-thiadiazaphospholes from 1-phenoxy-2-thiocyanatoethene

Journal Article · Thu Aug 20 04:00:00 EDT 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5615528

Dmitrichenko, M Yu; Rozinov, V G; Bychkova, T I; Donskikh, V I; Dolgushin, G V; Ratovskii, G V; Sergienko, L M

1-Phenoxy-2-thiocyanatoethene undergoes reaction with phosphorus pentachloride with the participation of two reaction centers, vinyl and thiocyanate groups, to form a phosphorus-containing heterocycle, a derivative of 1,3,4-thiazaphosph-2-ole. Transformations of the phosphorylation product were studied. The /sup 1/H, /sup 31/P, and /sup 13/C NMR spectra were recorded on a WP-200SY Bruker spectrometer at room temperature. The stabilization was carried out with respect to a deuterium signal in CDCl/sub 3/. The /sup 31/P NMR signals were recorded relative to 85% H/sub 3/PO/sub 4/ as external standard (the positive values designate shift to the weak field) with a heteronuclear broadband uncoupling from protons.

• OSTI ID: 5615528
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:3; ISSN JGCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ANTITHYROID DRUGS
AZOLES
CARBON 13
CARBON ISOTOPES
CARBONIC ACID DERIVATIVES
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE 35
CHLORINE COMPOUNDS
CHLORINE ISOTOPES
CHLOROFORM
CONFIGURATION INTERACTION
COUPLING
COUPLING CONSTANTS
DEUTERIUM COMPOUNDS
DRUGS
ETHERS
EVEN-ODD NUCLEI
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HETEROCYCLIC COMPOUNDS
HORMONE ANTAGONISTS
HYDROGEN 1
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYPERFINE STRUCTURE
INTERMEDIATE COUPLING
ISOMERIZATION
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
MONOMERS
NMR SPECTRA
NUCLEAR QUADRUPOLE RESONANCE
NUCLEI
ODD-EVEN NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SULFUR COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS CHLORIDES
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
PHOSPHORYLATION
RESONANCE
SPECTRA
SPIN ECHO
STABLE ISOTOPES
SYNTHESIS
THIAZOLES
THIOCYANATES
VINYL MONOMERS