Ion cyclotron resonance investigations of alkylation of (eta/sup 5/-C/sub 5/H/sub 5/)Ni/sup +/ and (eta/sup 5/-C/sub 5/H/sub 5/)Fe/sup +/ by methyl halides in the gas phase
Journal Article
·
· Inorg. Chem.; (United States)
A detailed study of the sequential alkylation of (eta/sup 5/-C/sub 5/H/sub 5/)Ni/sup +/ and (eta/sup 5/-C/sub 5/H/sub 5/)Fe/sup +/ by methyl bromide in the gas phase using the techniques of ion cyclotron resonance (ICR) spectroscopy is reported. A reaction mechanism for the alkylation process is proposed through the use of both ICR double resonance techniques and deuterium-labeled methyl bromide. The reactions of CpNi/sup +/ with C/sub 2/H/sub 5/Br and of CpNi/sup +/ and CpFe/sup +/ with CH/sub 3/X (X = F, Cl, I) are briefly discussed.
- Research Organization:
- California Inst. of Tech., Pasadena
- OSTI ID:
- 5280012
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 17:1; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKYLATION
BROMINATED ALIPHATIC HYDROCARBONS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
HALOGENATED ALIPHATIC HYDROCARBONS
IRON COMPOUNDS
KINETICS
MASS SPECTROSCOPY
METHYL BROMIDE
NICKEL COMPOUNDS
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS
SPECTROSCOPY
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ALKYLATION
BROMINATED ALIPHATIC HYDROCARBONS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
HALOGENATED ALIPHATIC HYDROCARBONS
IRON COMPOUNDS
KINETICS
MASS SPECTROSCOPY
METHYL BROMIDE
NICKEL COMPOUNDS
ORGANIC BROMINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
REACTION KINETICS
SPECTROSCOPY
TRANSITION ELEMENT COMPOUNDS