Ozonization of balkhashite
The stepwise ozonization of balkhashite in glacial acetic acid permits more than 75% of the carbon of the initial organic matter to be converted into a soluble form. The C/sub 7/-C/sub 25/ normal monocaboxylic acids, the C/sub 2/, and C/sub 4/-C/sub 21/ normal dicarboxylic acids, and ..gamma..-lactones of hydroxy dicarboxylic acids have been detected in the ozonization products by gas-liquid chromatography (GLC) and chromato-mass spectrometry. The yields of ozonization products and the component composition of the substances identified indicate a saturated cyclic and nonaromatic nature of balkhashite and the participation of the acids of natural fats in its formation. The composition of the water-insoluble acids from the ozonization of balkhashite reveals a similarity with the composition of the corresponding acids of certain shales.
- Research Organization:
- Lensovet Leningrad Technological Institute
- OSTI ID:
- 5236400
- Journal Information:
- Solid Fuel Chem. (Engl. Transl.); (United States), Journal Name: Solid Fuel Chem. (Engl. Transl.); (United States) Vol. 17:3; ISSN SFCHD
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
014000* -- Coal
Lignite
& Peat-- Combustion
ACETIC ACID
ACIDIFICATION
CARBON
CARBONACEOUS MATERIALS
CARBOXYLIC ACIDS
CHEMICAL COMPOSITION
CHEMICAL REACTIONS
CHROMATOGRAPHY
DICARBOXYLIC ACIDS
ELEMENTS
GAS CHROMATOGRAPHY
LIQUID COLUMN CHROMATOGRAPHY
MASS SPECTRA
MATERIALS
MONOCARBOXYLIC ACIDS
NONMETALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC MATTER
OZONIZATION
QUANTITY RATIO
ROCKS
SEDIMENTARY ROCKS
SEPARATION PROCESSES
SHALES
SOLUBILITY
SPECTRA