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Coherent precipitation of silicon nitride in silicon

Journal Article · · Appl. Phys. Lett.; (United States)
DOI:https://doi.org/10.1063/1.99722· OSTI ID:5220266
Coherent growth of ..cap alpha..-Si/sub 3/N/sub 4/ precipitates is observed in a silicon matrix after implantation of 150 keV N/sup +/ at a dose of 1 x 10/sup 18//cm/sup 2/ into (110) silicon. The near-channeling conditions lead to a band of discrete precipitates, 0.5 ..mu..m below the continuous, polycrystalline buried nitride layer. No misfit dislocations or strain contrast were observed in the silicon matrix despite a 10% lattice mismatch along the Si/sub 3/ N/sub 4/ (0001) direction and a 1% mismatch along directions perpendicular to (0001). The mismatch appears to be accommodated entirely within the precipitate by a mosaic structure consisting of single-crystal subunits, coherent with Si at the Si/sub 3/ N/sub 4/ (0001)/Si)111) interface, but incoherent perpendicular to these planes.
Research Organization:
Department of Chemical and Nuclear Engineering, University of New Mexico, Albuquerque, New Mexico 87131
OSTI ID:
5220266
Journal Information:
Appl. Phys. Lett.; (United States), Journal Name: Appl. Phys. Lett.; (United States) Vol. 52:21; ISSN APPLA
Country of Publication:
United States
Language:
English