Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Temperature dependence of the gas-phase self-reaction of HO/sub 2/ in the presence of NH/sub 3/

Journal Article · · J. Phys. Chem.; (United States)
OSTI ID:5218589
The dependence of the rate constant for the overall reaction HO/sub 2/ + HO/sub 2/ ..-->.. products on temperature (290 to 400 K) and concentration of NH/sub 3/ is reported. Analysis of the results yields values of ..delta..H/sup 0//sub 298/ = -13 +- 1.5 kcal/mol and ..delta..G/sup 0//sub 298/ = -3.3 +- 0.2 kcal/mol for the formation of the HO/sub 2/-NH/sub 3/ complex.
Research Organization:
Argonne National Lab., IL
OSTI ID:
5218589
Journal Information:
J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 84:8; ISSN JPCHA
Country of Publication:
United States
Language:
English