Selective oxidation of alcohols by oxoaminium salts (R/sub 2/N = O/sup +/X/sup -/
Journal Article
·
· J. Org. Chem.; (United States)
The selective oxidation of alcohols by use of an oxoaminium salt was investigated. The reaction proceeded clearly under mild condition with a satisfactory yield of carbonyl compounds uncomplicated by the presence of side products. The synthesis of oxoaminium salt IV was given. The oxidation of l-hexanol, 2-hexanol, and 3-hexanol by use of IVa (oxidant) in CH/sub 2/Cl/sub 2/ at room temperature was included. The oxidation rates of primary and secondary alcohols with IVa were studied. Primary alcohols were oxidized faster than secondary alcohols with IVa. 7 references, 2 figures, 2 tables.
- Research Organization:
- Tokyo Institute of Technology, Japan
- OSTI ID:
- 5170221
- Journal Information:
- J. Org. Chem.; (United States), Journal Name: J. Org. Chem.; (United States) Vol. 50:8; ISSN JOCEA
- Country of Publication:
- United States
- Language:
- English
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