Selective oxidation of primary alcohols to aldehydes by O/sub 2/ employing a trinuclear ruthenium carboxylate catalyst
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Though many reports describe trinuclear ruthenium carboxylates as catalysts, none of these systems utilize dioxygen as the primary oxidant. The authors have found Ru/sub 3/O(O/sub 2/CR)/sub 6/L/sub 3//sup n/ (R = CH/sub 3/ or C/sub 2/H/sub 5/; L = H/sub 2/O or PPh/sub 3/; n = 0, + 1) to be an efficient catalyst for the selective oxidation of primary alcohols to aldehydes and secondary alcohols to ketones by O/sub 2/ under mild conditions.
- Research Organization:
- Univ. of Florida, Gainesville
- OSTI ID:
- 6137529
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 109:12; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
090210 -- Alcohol Fuels-- Properties-- (1976-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALDEHYDES
CARBOXYLIC ACID SALTS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
DATA
ELEMENTS
EXPERIMENTAL DATA
HYDROXY COMPOUNDS
INFORMATION
KETONES
MEDIUM TEMPERATURE
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
OXYGEN
RUTHENIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALDEHYDES
CARBOXYLIC ACID SALTS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COMPLEXES
DATA
ELEMENTS
EXPERIMENTAL DATA
HYDROXY COMPOUNDS
INFORMATION
KETONES
MEDIUM TEMPERATURE
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDATION
OXYGEN
RUTHENIUM COMPLEXES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES