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Observation of photocurrent from band-to-band excitation of semiconducting p-type diamond thin film electrodes

Journal Article · · Journal of the Electrochemical Society
DOI:https://doi.org/10.1149/1.1837704· OSTI ID:516885
; ; ; ;  [1]
  1. Univ. of Tokyo (Japan). Dept. of Applied Chemistry

High quality semiconducting boron-doped polycrystalline diamond thin films were prepared on Si substrates via microwave plasma chemical vapor deposition. The resistivities of the lightly doped films were on the order of 10{sup 2} (Omega) cm. The photoelectrochemical behavior was studied with excimer lasers of several different wavelengths, including ArF (193 nm, 6.4 eV), KrF (248 nm, 5.0 eV), and XeF (351 nm, 3.53 eV). The photocurrent observed using the ArF laser was significantly greater than those observed with the KrF and XeF lasers. The authors propose that, for the ArF laser, the suprabandgap illumination was able to excite electrons into the conduction band, while the KrF and XeF lasers were not.

Sponsoring Organization:
USDOE
OSTI ID:
516885
Journal Information:
Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 6 Vol. 144; ISSN JESOAN; ISSN 0013-4651
Country of Publication:
United States
Language:
English

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