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Hot isostatic pressing of silicon nitride with boron nitride, boron carbide, and carbon additions

Journal Article · · Journal of the American Ceramic Society; (United States)
;  [1]
  1. National Aeronautics and Space Administration, Cleveland, OH (United States). Lewis Research Center

This paper reports how Si{sub 3}N{sub 4} test bars containing additions of BN, B{sub 4}C, and C, were hot isostatically pressed in Ta cladding at 1900{degrees} and 2050{degrees} C to 98.9% to 99.5% theoretical density. Room-temperature strength data on specimens containing 2 wt% BN and 0.5 wt% C were comparable to data obtained for Si{sub 3}N{sub 4} sintered with Y{sub 2}O{sub 3}, Y{sub 2}O{sub 3} and Al{sub 2}O{sub 3} or ZrO{sub 2}. The 1370{degrees} C strengths were less than those obtained for additions of Y{sub 2}O{sub 3} or ZrO{sub 2} but greater than those obtained from a combination of Y{sub 2}O{sub 3} and Al{sub 2}O{sub 3}. Scanning electron microscope fractography indicated that, as with other types of Si{sub 3}N{sub 4}, room-temperature strength was controlled by processing flaws. The decrease in strength at 1370{degrees} C was typical of Si{sub 3}N{sub 4} having an amorphous grain-boundary phase. The primary advantage of non-oxide additions appears to be in facilitating specimen removal from the Ta cladding.

OSTI ID:
5154475
Journal Information:
Journal of the American Ceramic Society; (United States), Journal Name: Journal of the American Ceramic Society; (United States) Vol. 72:5; ISSN 0002-7820; ISSN JACTA
Country of Publication:
United States
Language:
English